N,N’-Bis(salicylidene)ethylenediaminocobalt(II)

Specification:
| Synonyms N2O9115YTK; Salicylaldehyde ethylenediimine cobalt; Cobalt, ((2,2′-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N’,O,O’)-, (SP-4-2)-; SCHEMBL510827; cobalt(2+); AI3-30876; (Ethylenebis(nitrilomethylidyne)-2,2′-diphenolato)cobalt(II); cobalt(2+) 2-{[(2-{[(2-oxidophenyl)methylidene]amino}ethyl)imino]methyl}benzenolate; N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II); SALCOMINE; | IUPAC Name cobalt(2+);2-[2-[(2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolate; | Canonical SMILES C1=CC=C(C(=C1)C=NCCN=CC2=CC=CC=C2[O-])[O-].[Co+2]; | InChI InChI=1S/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2; | InChI Key NPAQSKHBTMUERN-UHFFFAOYSA-L; | Solubility Soluble in benzene, chloroform, and pyridine; | Color/Form Red crystals from DMF;Dark brown powder; | Complexity 298 | Covalently-Bonded Unit Count 2 | Decomposition When heated to decomposition it emits toxic fumes of /nitrous oxide/.; | EC Number 238-012-5 | Exact Mass 325.039g/mol | H-Bond Acceptor 4 | Heavy Atom Count 21 | Monoisotopic Mass 325.039g/mol | Other Experimental Ionization energy (IE): 7.52 eV;No rapid reaction with air. No rapid reaction with water.; | Physical Description SALCOMINE is a solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called “Schiff’s bases.” Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which it behaves as an oxygen carrier.; | Rotatable Bond Count 5 | Stability Stable under recommended storage conditions.; | Topological Polar Surface Area 70.8A^2 | UNII N2O9115YTK

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